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RA (Radiocommunications Agency): An executive agency of the United Kingdom Department of Trade and Industry, responsible for the manage ment of the nonmilitary radio spectrum in the UK, which involves inter national representation, commissioning research, allocating spectrum and licensing its use, as well as keeping the radio spectrum clean TIA (Telecommunications Industry Association): A trade association serving the communications and information technology industry, with proven strengths in market development, trade shows, domestic and inter national advocacy, standards development, and enabling e-business UMTS (Universal Mobile Telecommunications System) Forum: A nonprofit, cross-industry organization that is uniquely committed to the successful introduction and development of UMTS/IMT-2000 third genera tion mobile communications systems UWCC (Universal Wireless Communications Consortium): An inter national consortium of more than 100 wireless carriers and vendors sup porting the TDMA, EDGE, and WIN technology standards and their interoperability with GSM and UMTS.

WAP Forum: An industry association that has developed the de facto world standard for wireless information and telephony services on digital mobile phones and other wireless terminals The primary goal of the WAP Forum is to bring together companies from all segments of the wireless industry value chain to ensure product interoperability and growth of wireless market WCA (Wireless Communications Association International): A non profit trade association representing the wireless broadband industry..

Catalysts An extremely large number of catalysts and different catalyst combinations are known to catalyze the polymerization of alkenes In our discussion we will classify them as Ziegler-Natta catalysts and one-component transition-metal catalysts The first successful catalyst used by Ziegler and coworkers38 ,231,232 for the polymerization of ethylene was TiCl 4 and Et3Al Other alkylaluminum compounds (EhAICI, Et3AhCI3, isoBu3AI), also termed activators or cocatalysts, were employed later Prepared in situ, the two components form an unstable precipitate in an inert solvent, which is generally a hydrocarbon In a similar approach Natta and coworkers first used Ziegler's original catalyst combination,239 then later preformed purple TiCl3 for the polymerization of propylene 34,240 They found that a mixture of crystalline and amorphous polymers was formed 33 This observation led to the development of stereoregular polymerization catalysts and processes.

Preface. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ix Acknowledgments . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . xv

It is of historical interest to note that Max Fischer, working during World War II in the German industry, while investigating how solid waxes were formed in AlCI 3catalyzed oligomerization of ethylene producing synthetic lubricant oils, disclosed in a patent application in 1943 (published only in 1953 because of war aftermath difficulties)241 that ethylene is polymerized at moderate pressures and temperatures by a catalyst composed of AICI 3, a reducing metal such as AI, and TiCl 4 to solid polyethylene No characterization of the polymer or any suggestions as to the nature of the polymerization was given.

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Dosimeters Personnel should be supplied with direct reading dosimeters, such as pocket dosimeters, so that immediate readings are available at the time of exposure. These devices do not provide a means of permanent record keeping and cannot discriminate between types or energies of radiation. All personnel should, therefore, wear lm badges or thermoluminescent devices (TLDs) in addition to direct reading dosimeters. For a more detailed description of these devices please refer to 4 (Figs 4-10 and 4-13 with accompanying text).

A reinvestigation in the 1980s showed that the polyethylene formed in the Max Fischer polymerization, when the temperature is kept at about 150 C, is identical to that of linear Ziegler polyethylene with limited methyl branching 42 Ethylene, when reacted under similar conditions with AICl 3 and AI, is known to give ethylaluminum sesquichloride 154 It was subsequently shown 242 that in this system (CI 2AlCH 2h and (CI 2AlhCHCH 3 are also formed Any ethylaluminum compound on addition of TiCl 4 forms an active Ziegler catalyst Fischer thus, not knowing the nature of his polymerization or the linearity of the product, in the early 1940s already produced HDPE and was a forerunner of the Ziegler-Natta polymerization Linear polyethylene can further also be considered as polymethylene.